Stable Radical Anions in Photocatalysis
In the recent past visible light photoredox catalysis has gained enormous attention as an energy-efficient and versatile method for chemical synthesis.(1, 2) In my presentations, I will mainly talk about our recent work on visible light photoredox catalysis using stable radical anions of commercially available inexpensive organic dyes.(3-7) The applications of bioinspired consecutive photoinduced electron transfer (conPET)(3, 4, 6, 7) and sensitization initiated electron transfer (SenI-ET)(5) processes will be discussed in the context of breaking and making of stable chemical bonds for useful synthetic transformations.
1. B. Konig, Eur. J. Org. Chem., 1979-1981 (2017).
2. I. Ghosh, L. Marzo, A. Das, R. Shaikh, B. Konig, Acc. Chem. Res. 49, 1566-1577 (2016).
3. I. Ghosh, T. Ghosh, J. I. Bardagi, B. Konig, Science 346, 725-728 (2014).
4. I. Ghosh, B. Konig, Angew. Chem. Int. Ed. 55, 7676-7679 (2016).
5. I. Ghosh, R. S. Shaikh, B. Konig, Angew. Chem. Int. Ed. 56, 8544-8549 (2017).
6. A. Das, I. Ghosh, B. Konig, Chem. Commun. 52, 8695-8698 (2016).
7. L. Marzo, I. Ghosh, F. Esteban, B. Konig, ACS Catal. 6, 6780-6784 (2016).